Concept information
Terme préférentiel
Born-Oppenheimer approximation
Définition(s)
- In quantum chemistry and molecular physics, the Born–Oppenheimer (BO) approximation is the best-known mathematical approximation in molecular dynamics. Specifically, it is the assumption that the wave functions of atomic nuclei and electrons in a molecule can be treated separately, based on the fact that the nuclei are much heavier than the electrons. Due to the larger relative mass of a nucleus compared to an electron, the coordinates of the nuclei in a system are approximated as fixed, while the coordinates of the electrons are dynamic. The approach is named after Max Born and J. Robert Oppenheimer who proposed it in 1927, in the early period of quantum mechanics. (Wikipedia, The Free Encyclopedia, https://en.wikipedia.org/wiki/Born%E2%80%93Oppenheimer_approximation)
Concept(s) générique(s)
Synonyme(s)
- Born-Oppenheimer expansion
Traductions
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français
URI
http://data.loterre.fr/ark:/67375/MDL-VR7G3M4S-L
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